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The 4th International Symposium on Polybenzoxazines ISPBZ 2021 will take place virtually from 31 May to 4 June 2021 and is organised by the Luxembourg Institute of Science and Technology (LIST). Polybenzoxazines are a new generation of polymer thermosets matching with the requirements of high performance industries like aerospace or automotive. On top of that, the versatility and scalability of these polymers make them highly attractive for the elaboration of advanced materials, with specific stimulus responsive behaviours. The symposium will focus on the most recent advances in the understanding of benzoxazine common properties, as well as the latest progresses towards their technological exploitation. A special attention will be given toward their industrial development, from their synthesis to their exploitation in concrete applications.